Ahrensite, γ-Fe2SiO4, a new shock-metamorphic mineral from the Tissint meteorite: implications for the Tissint shock event on Mars

Ahrensite (IMA 2013-028), γ-Fe2SiO4, is the natural Fe-analog of the silicate-spinel ringwoodite (γ-Mg2SiO4). It occurs in the Tissint Martian meteorite, where it forms through the transformation of the fayalite-rich rims of olivine megacrysts or Fe-rich microphenocrysts in contact with shock melt pockets. We report the first comprehensive set of crystallographic, spectroscopic, and quantitative chemical analysis of type ahrensite, and show that concentrations of ferric iron and inversion in the type material of this newly approved mineral are negligible. We also report the occurrence of nanocrystalline ringwoodite in strained olivine and establish correlations between grain size and distance from melt pockets. The ahrensite and ringwoodite crystals show no preferred orientation, consistent with random